To overwrite a Windows 7 password, one can boot from a Ubuntu LiveCD and run chntpw.
Unfortunately, installing chntpw is not so easy:
$ sudo apt-get install chntpw E: Unable to locate package chntpw 12 Answers
First open the Ubuntu Software Center, in the Edit menu click Software Sources..., and in the window that appears enable universe as seen below:

Then run sudo apt-get update.
You should now be able to install chntpw using sudo apt-get install chntpw.
Do this from the terminal
sudo add-apt-repository universe sudo apt-get update sudo apt-get install chntpw